Non-premixed ammonia combustion in tailored ceramic porous inert media

10 - Non-premixed ammonia combustion in tailored ceramic porous inert media

Summary

The project focuses on the thermochemical energy conversion process of the carbon-free chemical energy carrier ammonia and of ammonia/hydrogen mixtures. Ammonia is considered as one of the future energy and hydrogen carriers, especially in terms of long-distance transport since its thermal properties are similar to those of propane and it can easily be liquefied for storage and transport with an established transportation network. However, the combustion of ammonia poses considerable challenges. The three major challenges are its low burning velocity compared to hydrocarbons resulting in poor flame stability, extremely high levels of nitrogen oxide formation and high toxicity even at trace levels. Conventional approaches to address these challenges are the addition of highly reactive fuels like hydrogen or methane to address the issue of flame stability, conversion in staged fuel rich/lean processes to address the high NOx formation and post treatment for avoiding unburnt ammonia emissions. We propose to address all challenges at once by a novel concept for non-premixed combustion of ammonia in Porous Inert Media (PIM). Combustion in PIM can increase burning velocities by more than one order of magnitude compared with non-PIM combustion due to heat recirculation through the solid phase. Heat recirculation combined with the thermal inertia of the solid phase resolves the issue of flame stability. The non-premixed approach results in high temperatures of the initial fuel rich or pure fuel streams decomposing ammonia without significant NOx formation, while the good mixing and temperature homogenization effects by the flow through the PIM lead to a complete burnout of remaining ammonia in a post-combustion zone. In order to realize such concept, tailored high temperature-resistant materials are required, both in terms of geometry as well as spatial distribution of thermal properties. Additive manufacturing (ADM) of PIM structures from composite ceramic materials is needed to control the process through customized properties regarding heat conduction, radiation properties, dispersion and the flow field. The fundamental research and design of the non-premixed PIM burner for ammonia and ammonia/hydrogen-mixtures requires a strong interdisciplinary research team in the fields of high-fidelity experiments for combustion in PIM (EXP, KIT), detailed pore-resolved numerical simulations (SIM, KIT) and additive manufacturing methods for thermal shock and corrosion-resistant functional components (ADM, TU BAF).

Project10

Research Team

Trimis

Prof. Dr.-Ing. Dimosthenis Trimis

Principal Investigator (PI)

Karlsruhe Institute of Technology
Engler-Bunte-Institute
dimosthenis.trimis(at)kit.edu
Stein

Prof. Dr. Oliver T. Stein

Principal Investigator (PI)

Karlsruhe Institute of Technology
Engler-Bunte-Institute
oliver.t.stein(at)kit.edu


Azernis

Prof. Dr.-Ing. habil. Christos G. Aneziris

Principal Investigator (PI)

TU Bergakademie Freiberg
Institute of Ceramics, Refractories and Composite Materials
Christos.Aneziris(at)ikfvw.tu-freiberg.de
Brachhold

Dr.-Ing. Nora Brachhold

Principal Investigator (PI)

TU Bergakademie Freiberg
Institute of Ceramics, Refractories and Composite Materials
Nora.Brachhold(at)ikfvw.tu-freiberg.de
 
Stelzner

Dr.-Ing. Björn Stelzner

Researcher

Karlsruhe Institute of Technology
Engler-Bunte-Institute
bjoern.stelzner(at)kit.edu
Zirwes

Dr.-Ing. Thorsten Zirwes

Researcher

University of Stuttgart
Institute for Combustion Technology
thorsten.zirwes(at)itv.uni-stuttgart.de


Kretzler

M.Sc. Daniel Kretzler

Doctoral Researcher

Karlsruhe Institute of Technology
Engler-Bunte-Institute
daniel.kretzler(at)kit.edu
Puri

M.Sc. Rishabh Puri

Doctoral Researcher

Karlsruhe Institute of Technology
Engler-Bunte-Institute
rishabh.puri(at)kit.edu


Bock

Dipl.-Ing. Benjamin Bock-Seefeld

Doctoral Researcher

TU Bergakademie Freiberg
Institute of Ceramics, Refractories and Composite Materials
benjamin.bock(at)ikfvw.tu-freiberg.de